the only thing I can say is i left a tank full of tap water in my shed for a month or two asnd it got that too. It is gross though and smells like a dead fish lol. of course it is still there.... :-( lazy...
I couldnt get a picture, once I skimmed it off its gone for now.
Only thing I can think of is recently I put a lid over the top of the hood, not over the water but over the lighting hood. I did this because the cat was looking very curiously at jumping into the tank. Although it had been on there for a couple of weeks with no sign of anything.